Thanks Buddy. Actually I thought if we are using 'His', then probably we need to frame like 'I cannot imagine his chance/possibility of getting the first mark'. Perhaps, I am not sure about this formation.
in your question we never can use he
but we can also use him and his
that grammatically "his" is more better but in speech "him" is common too.
and if we want to use he we can change it into:
I can not imagine (that) he get the first mark.