Sorry GM, but I wouldn't go along with you on that either.
In traditional grammar, determinatives form a subclass of adjectives. Thus the "which" in "Which car is yours"? was treated as a kind of adjective based on some vague idea that it 'modified' the noun "car" (which it doesn't). But in modern grammar, determinatives are treated as a distinct primary group, so this "which" is a determinative, not an adjective.
In the case of "Which is yours"?, things are a tad complicated. The crucial thing about "which" is that it differs from all the other interrogative words in having a property called 'selective', implying that the answer to the question is to be selected from some definite set; in this case the set is "some cars". Function-wise, this "which" is called a 'fused determiner-head', so in a tree diagram, "which" would carry the function label 'Determiner-Head' and the category label 'Deteminative'.